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| Article Name : | | | KINETICS AND MECHANISM OF OXIDATION OF L-ASPARTIC ACID BY POTASSIUM PERMANGANATE IN AQUEOUS ACID MEDIUM | | Author Name : | | | J. S. DIGGIKAR | | Publisher : | | | Ashok Yakkaldevi | | Article Series No. : | | | GRT-2337 | | Article URL : | |  | Author Profile View PDF In browser | | Abstract : | | | The oxidation of L-aspartic acid by potassium permanganate in aqueous perchloric acid medium has been studied. The reaction is first order dependence on potassium permanganate concentration and order in L-aspartic acid is fractional which suggests intermediate complex formation between L-aspartic acid and potassium permanganate. The thermodynamic parameters are reported. The rate was found to increase with increasing concentration of perchloric acid. Suitable mechanism is proposed and rate laws derived explain the results obtained. | | Keywords : | | |
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